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If it is just the chaff going mouldy I won't worry. It is very unusual for good seed to go mouldy. It is a different type of rot that affects seed. They go soft rather than mouldy. I just leave chaff,it soon disappears and the seed grow through it. Susan
I surface sow Rhododendron seed on peat moss and have good results. I cover the pot with plastic and keep it fairly warm (room temperature). After germination I remove the plastic cover and place the pot somewhat cooler (15-18 degrees C.) Growth in the first year is usually slow.
I do the same way, and agree that vermiculite is not good with rhododendron. Rhododendrons need acid environment. I keep the seed pots covered with plastic for until when it is time to prick them out, and only water underneath.